S. Kitagawa et al., RAPID ELECTROCONCENTRATION IN A TUBE OF 25-40 MICROLITERS UNDER A RELATIVELY LOW APPLIED VOLTAGE, Analytical sciences, 12(4), 1996, pp. 581-586
Electroconcentration can be performed using a very simple apparatus an
d a simple operational procedure. The apparatus is composed of one tub
e, two electrodes and a power supply. The total sample solution employ
ed for electroconcentration was just 25-40 mu l. After a tube of silic
one rubber (i.d. 1 mm, 30-50 mm long) was filled with a sample solutio
n, an electric voltage was applied along the tube, and a charged solut
e was forced to migrate to the end of the tube. With an application of
200-400 V for only 2-4 min, the concentration of the solute was enhan
ced up to 10 times. In the present electroconcentration, the sample is
concentrated in a few microliters. Electroconcentration by electrode
transfer is also proposed.