ELECTROSPRAY MASS-SPECTROMETRIC DETECTION OF UNSTABLE RHENIUM COMPLEXES AS REACTION INTERMEDIATES OF PHOTOCHEMICAL CO2-FIXATION

Authors
HORI H ISHITANI O KOIKE K TAKEUCHI K IBUSUKI T
Citation
H. Hori et al., ELECTROSPRAY MASS-SPECTROMETRIC DETECTION OF UNSTABLE RHENIUM COMPLEXES AS REACTION INTERMEDIATES OF PHOTOCHEMICAL CO2-FIXATION, Analytical sciences, 12(4), 1996, pp. 587-590
Citations number
24
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical sciences → ACNP
ISSN journal
09106340
Volume
12
Issue
4
Year of publication
1996
Pages
587 - 590
Database
ISI
SICI code
0910-6340(1996)12:4<587:EMDOUR>2.0.ZU;2-Z
Abstract
Reaction intermediates of CO2-photofixation using [Re(bpy)(CO)(3)PPh(3 )](+)(bpy=2,2'-bipyridine) have been studied by electrospray mass spec trometry. A triethanolamine (TEOA) complex, [Re(bpy)(CO)(3)(TEOA)](+), was detected for the first time as a key intermediate. Electrospray m ass spectrometry was found quite useful for detecting and identifying unstable photoreaction intermediates of rhenium complexes.