SYNTHESIS IN THE MELT AND CHARACTERIZATION OF CONDENSED BINARY PHOSPHATES BANH4(PO3)(3), BINH4P4O12 AND TI(NH4)(2)P4O13

Authors
SELEVICH AF LEVCHIK SV LYAKHOV AS LEVCHIK GF LESNIKOVICH AI CATALA JM
Citation
Af. Selevich et al., SYNTHESIS IN THE MELT AND CHARACTERIZATION OF CONDENSED BINARY PHOSPHATES BANH4(PO3)(3), BINH4P4O12 AND TI(NH4)(2)P4O13, Journal of solid state chemistry, 125(1), 1996, pp. 43-46
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
125
Issue
1
Year of publication
1996
Pages
43 - 46
Database
ISI
SICI code
0022-4596(1996)125:1<43:SITMAC>2.0.ZU;2-K
Abstract
Barium-ammonium polyphosphate (BaNH4(PO3)(3)), bismuth-ammmonium cyclo tetraphosphate (BiNH4P4O12), and titanium-ammonium tetraphosphate (Ti( NH4)(2)P4O13) have been synthesized in the melt of ammonium polyphosph ate (NH4PO3). The prepared phosphates were characterized by chemical a nalysis, thin layer chromatography, and X-ray diffraction of powders. BiNH4P4O12 was found to crystallize in the cubic system, space group < I(4)over bar 3d> with the unit-cell parameter a = 15.105(2) Angstrom. Thermal decomposition behavior of the phosphates was studied by thermo gravimetry and crystalline products of degradation were identified. (C ) 1996 Academic Press, Inc.