CP(CO)(2)MNN(BZ)CH2CH2, THE FIRST MONO-CO ORDINATE AZIRIDINE COMPLEX

Authors
VONBECKERATH S LORENZ IP FAWZI R STEIMANN M
Citation
S. Vonbeckerath et al., CP(CO)(2)MNN(BZ)CH2CH2, THE FIRST MONO-CO ORDINATE AZIRIDINE COMPLEX, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(7), 1996, pp. 959-962
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
51
Issue
7
Year of publication
1996
Pages
959 - 962
Database
ISI
SICI code
0932-0776(1996)51:7<959:CTFMOA>2.0.ZU;2-K
Abstract
The photolytically induced CO-substitution reaction of CpMn(CO)(3) wit h N-benzyl-aziridine leads to the first mono coordinate aziridine comp lex, Cp(CO)(2)MnN(Bz)CH2CH2. It is stable against thermal C2H4 elimina tion up to 135 degrees C. No nitrene complexes {Cp(CO)(2)Mn}(n)NBz (n = 1, 2) were detected. The X-ray structure analysis of Cp(CO)(2)MnN(Bz )CH2CH2 shows the intact three-membered ring ligand and the pyramidal configuration of the nitrogen atom.