Be. Dainson et al., APPLICATION OF VARIABLE-STRUCTURE MODELS TO OSCILLATORY AND SPATIALLY-DEPENDENT PROCESSES, Industrial & engineering chemistry research, 35(8), 1996, pp. 2590-2595
In this paper, the variable structure model (VSM) approach is applied
to modeling and parameter estimation in processes exhibiting simple an
d complex relaxation oscillations. The approach reduces the full model
to two simple submodels and permanently chooses the submodel which ha
s a better performance in the description of the input-output behavior
of the process. The degree to which the approach will adequately appr
oximate the true process dynamics increases with the system stiffness.
Excellent performance of the approach is demonstrated in both online
and off-line parameter estimation for a single CSTR as well as for a t
rain of reactors with the Belousov-Zhabotinski or polynomial kinetics.