INFINITE DILUTION PARTIAL MOLAR VOLUMES OF AQUEOUS SOLUTES OVER WIDE RANGES OF CONDITIONS

Authors
OCONNELL JP SHARYGIN AV WOOD RH
Citation
Jp. Oconnell et al., INFINITE DILUTION PARTIAL MOLAR VOLUMES OF AQUEOUS SOLUTES OVER WIDE RANGES OF CONDITIONS, Industrial & engineering chemistry research, 35(8), 1996, pp. 2808-2812
Citations number
17
Categorie Soggetti
Engineering, Chemical
Journal title
Industrial & engineering chemistry research → ACNP
ISSN journal
08885885
Volume
35
Issue
8
Year of publication
1996
Pages
2808 - 2812
Database
ISI
SICI code
0888-5885(1996)35:8<2808:IDPMVO>2.0.ZU;2-I
Abstract
Data for the partial molar volume at infinite dilution for several gas eous solutes and H3BO3 in water have been correlated using a generaliz ed Krichevskii parameter. The result is a simple function for <(upsilo n)over bar>(infinity)(1) in terms of the water density and compressibi lity for conditions from ambient to 125 K and 40 MPa. The accuracy is much better with only two parameters than with a previous five-paramet er model.