Av. Sumant et al., STUDIES ON HOT-FILAMENT CHEMICAL-VAPOR-DEPOSITION OF DIAMOND ONTO ALUMINUM-OXIDE, Materials science & engineering. B, Solid-state materials for advanced technology, 39(3), 1996, pp. 5-9
In situ two-step hot filament chemical vapor deposition (HFCVD) was de
veloped to synthesize diamond films on aluminum oxide (Al2O3) substrat
es. The first step at higher temperature leads to precipitation of dia
mond-like carbon (DLC) and aluminum carbide (Al4C3) phases on the subs
trate surface, which promote enhanced nucleation of diamond growth dur
ing the subsequent second step of deposition. The presence of carbide
phase in the interface region is found to lead to [100] oriented growt
h of diamond as well as enhanced adhesion properties.