The in situ x-ray reflectivity measurements during linear and isotherm
al annealings of a W/Si multilayer (ML) were performed, and successive
disappearance and reappearance of the second and third ML Bragg maxim
a between 400 and 500 degrees C were observed. Such behavior is direct
evidence of a long-range interface shift, and was found to be connect
ed with a substantial decrease of the electronic density of the expand
ing originally W layers and the ML period. Surprisingly, the changes t
ake place without smearing-out the interfaces. The results are explain
ed by the Si diffusion into the W layers. (C) 1996 American Institute
of Physics.