P. Reschiglian et al., EXPERIMENTAL-STUDY ON THE RETENTION OF SILICA PARTICLES IN GRAVITATIONAL FIELD-FLOW FRACTIONATION - EFFECTS OF THE MOBILE-PHASE COMPOSITION, Journal of chromatography, 740(2), 1996, pp. 245-252
Citations number
26
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
Effects of mobile phase composition can play an effective role in modu
lating the retention of particles in gravitational field-flow fraction
ation (GFFF), the simplest and cheapest among field-flow fractionation
(FFF) techniques. In the framework of an optimized procedure for the
GFFF characterization of particulate systems, an experimental approach
to the effects of the mobile phase composition on the retention of si
lica particles retention is presented. The role of the ionic strength
and the presence of surfactant are emphasized, with special regards to
the shape of the particles. Moreover, the first experimental evidence
of potential-barrier GFFF is reported.