SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MACROCYCLIC CARBOHYDRATE-DERIVATIVES OBTAINED FROM CATALYTIC METATHESIS REACTION WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN

Authors
DESCOTES G RAMZA J BASSET JM PAGANO S GENTIL E BANOUB J
Citation
G. Descotes et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MACROCYCLIC CARBOHYDRATE-DERIVATIVES OBTAINED FROM CATALYTIC METATHESIS REACTION WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN, Tetrahedron, 52(33), 1996, pp. 10903-10920
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
33
Year of publication
1996
Pages
10903 - 10920
Database
ISI
SICI code
0040-4020(1996)52:33<10903:SASCOM>2.0.ZU;2-D
Abstract
Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis rea ctions of di- and tri-substituted omega-unsaturated glucose, and gluco samine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem m ass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds. Copyright (C) 1996 Elsevier Sc ience Ltd