Ct. Li et al., CH2CL2 DECOMPOSITION BY USING A RADIOFREQUENCY PLASMA SYSTEM, Journal of chemical technology and biotechnology, 66(4), 1996, pp. 382-388
In this study, a radio-frequency plasma system was used to decompose a
dichloromethane (CH2Cl2) containing gas. Analyses of the reactants an
d final products were conducted by using Fourier Transform Infrared Sp
ectroscopy. Then, the effects of plasma operation-parameters, includin
g the gas flow rate, the feeding CH2Cl2 concentration, the equivalence
ratio phi (=stoichiometric O-2 needed/actual O-2 used) and the input
power wattage, for CH2Cl2 decomposition and for the fraction of total
carbon input converted into CO2 and CO were investigated. Mole fractio
n profiles for each experimental condition were determined for the rea
ctants (CH2Cl2 and O-2) and for CO, CO2, H2O, HCl, CHCl3, CCl4, COCl2,
C2HCl3 and C2Cl4. In addition, the possible reaction pathways were bu
ilt up and discussed.