RUTHENIUM(III)-SCHIFF BASE COMPLEX-CATALYZED OXIDATION OF SECONDARY ALCOHOLS BY N-METHYLMORPHOLINE-N-OXIDE OR THALLIUM(III) ACETATE

Authors
TONY KJ MAHADEVAN V RAJARAM J SWAMY CS
Citation
Kj. Tony et al., RUTHENIUM(III)-SCHIFF BASE COMPLEX-CATALYZED OXIDATION OF SECONDARY ALCOHOLS BY N-METHYLMORPHOLINE-N-OXIDE OR THALLIUM(III) ACETATE, International journal of chemical kinetics, 28(9), 1996, pp. 657-664
Citations number
25
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
28
Issue
9
Year of publication
1996
Pages
657 - 664
Database
ISI
SICI code
0538-8066(1996)28:9<657:RBCOOS>2.0.ZU;2-O
Abstract
The Ru(III) Schiff base complex, [Ru(L)Cl-2]Cl; L = bis(picolinaldehyd e) omicron-phenylenediimine, catalyzes the oxidation of secondary alco hols by N-methylmorpholine-N-oxide(NMO) or thallium(III) acetate as ox idant. Kinetic studies showed the formation of Ru(V) species as the ac tive intermediate. (C) 1996 John Wiley & Sons. Inc.