UNPRECEDENTED STEREOCHEMICAL REVERSAL FROM ALKYL TO ARYL SUBSTITUENTSIN THE JOHNSON-CLAISEN REARRANGEMENT OF METHYL 3-HYDROXY-2-METHYLENEALKANOATES

Authors
BASAVAIAH D PANDIARAJU S KRISHNAMACHARYULU M
Citation
D. Basavaiah et al., UNPRECEDENTED STEREOCHEMICAL REVERSAL FROM ALKYL TO ARYL SUBSTITUENTSIN THE JOHNSON-CLAISEN REARRANGEMENT OF METHYL 3-HYDROXY-2-METHYLENEALKANOATES, Synlett, (8), 1996, pp. 747
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):8<747:USRFAT>2.0.ZU;2-S
Abstract
An unprecedented stereochemical reversal from alkyl to aryl substituen ts in the Johnson-Claisen rearrangement of methyl 3-hydroxy-2-methylen ealkanotes with triethyl orthoacetate with plausible mechanism has bee n described.