DIASTEREOSELECTIVE CARBOMETALATION OF DELTA-MONOSUBSTITUTED AND GAMMA-DELTA-BISUBSTITUTED Z-VINYL METALS

Authors
BAHR A MAREK I NORMANT JF
Citation
A. Bahr et al., DIASTEREOSELECTIVE CARBOMETALATION OF DELTA-MONOSUBSTITUTED AND GAMMA-DELTA-BISUBSTITUTED Z-VINYL METALS, Tetrahedron letters, 37(33), 1996, pp. 5873-5876
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
33
Year of publication
1996
Pages
5873 - 5876
Database
ISI
SICI code
0040-4039(1996)37:33<5873:DCODAG>2.0.ZU;2-P
Abstract
the allylzincation reaction of delta-substituted and gamma-delta-bisub stituted Z vinyl metals proceeds highly diastereaselectively and repre sents a synthetic approach to construct four stereogenic centers from two preexisting ones in a single-pot operation. Copyright (C) 1996 Pub lished by Elsevier Science Ltd