SECONDARY ISOTOPE EFFECTS IN DIOXIRANE EPOXIDATIONS - CONCERTED OR STEP-WISE MECHANISM

Authors
ANGELIS Y ZHANG XJ ORFANOPOULOS M
Citation
Y. Angelis et al., SECONDARY ISOTOPE EFFECTS IN DIOXIRANE EPOXIDATIONS - CONCERTED OR STEP-WISE MECHANISM, Tetrahedron letters, 37(33), 1996, pp. 5991-5994
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
33
Year of publication
1996
Pages
5991 - 5994
Database
ISI
SICI code
0040-4039(1996)37:33<5991:SIEIDE>2.0.ZU;2-M
Abstract
The inverse alpha- and beta-secondary isotope effects found for the ep oxidation reaction of dimethyl dioxirane (DMD) with alkenes support a non polar concerted mechanism. Copyright (C) 1996 Elsevier Science Ltd