A. Aronne et al., FT INFRARED-SPECTROSCOPY OF THE DEVITRIFICATION OF LITHIUM GERMANATE GLASSES, Physics and Chemistry of Glasses, 37(4), 1996, pp. 134-137
A series of amorphous and crystalline lithium germanates containing up
to 25 mol% Li2O, are studied by FTIR. The glasses are found to devitr
ify in a number of steps. In the primary step, above T-g. the glasses
undergo a transformation with a strong exothermic effect which corresp
onds to almost no crystal growth. The nature of this process is invest
igated and discussed.