THE PREPARATION OF DIALKYLTHIOPHOSPHONATOAMINES - X-RAY STRUCTURES OF(ETO)(2)PSNHC6H4NO2 AND [(ETO)(2)PSNHC6H4NO2](2)PDCL2

Authors
PHILLIPS JR WILLIAMS DJ SLAWIN AMZ WOOLLINS JD
Citation
Jr. Phillips et al., THE PREPARATION OF DIALKYLTHIOPHOSPHONATOAMINES - X-RAY STRUCTURES OF(ETO)(2)PSNHC6H4NO2 AND [(ETO)(2)PSNHC6H4NO2](2)PDCL2, Polyhedron, 15(21), 1996, pp. 3725-3729
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
21
Year of publication
1996
Pages
3725 - 3729
Database
ISI
SICI code
0277-5387(1996)15:21<3725:TPOD-X>2.0.ZU;2-R
Abstract
Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = B u, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the ti tle compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free c ompound and its palladium complex. In the palladium complex, the ligan ds are tilted with respect to the coordination plane. Copyright (C) 19 96 Elsevier Science Ltd