H-1-NMR STUDIES OF PALLADIUM COMPLEXES WITH TRIDENTATE CHELATES, E-S(O)-E (E=P,AS) AND THEIR NOVEL ASYMMETRIC ANALOG

Authors
SIAH SY MOK KF LEUNG PH
Citation
Sy. Siah et al., H-1-NMR STUDIES OF PALLADIUM COMPLEXES WITH TRIDENTATE CHELATES, E-S(O)-E (E=P,AS) AND THEIR NOVEL ASYMMETRIC ANALOG, Polyhedron, 15(21), 1996, pp. 3915-3918
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
21
Year of publication
1996
Pages
3915 - 3918
Database
ISI
SICI code
0277-5387(1996)15:21<3915:HSOPCW>2.0.ZU;2-M
Abstract
Three stable palladium(II) complexes, [Pd{Ph(2)ECH(2)CH(2)S(O)CH(2)CH( 2)E'Ph(2)}Cl]ClO4 (where E, E' = As, 1; E, E' = P, 2; E = As, E' = P, 3), were prepared. The H-1 NMR studies on these square-planar complexe s revealed the stereochemically favoured ring conformations adopted by the tridentate ligands in solution. Copyright (C) 1996 Elsevier Scien ce Ltd