FORMATION OF SECONDARY OZONIDES IN THE GAS-PHASE OZONOLYSIS OF SIMPLEALKENES

Authors
NEEB P HORIE O MOORTGAT GK
Citation
P. Neeb et al., FORMATION OF SECONDARY OZONIDES IN THE GAS-PHASE OZONOLYSIS OF SIMPLEALKENES, Tetrahedron letters, 37(52), 1996, pp. 9297-9300
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
52
Year of publication
1996
Pages
9297 - 9300
Database
ISI
SICI code
0040-4039(1996)37:52<9297:FOSOIT>2.0.ZU;2-#
Abstract
Secondary propene ozonide and isobutene ozonide were formed in the gas -phase ozonolysis of ethene with added acetaldehyde and acetone, respe ctively. Combined with the formation of hydroperoxymethyl formate and methoxymethyl hydroperoxide in the ethene-ozone reaction system in the presence of HCOOH and CH3OH, respectively, formation of the secondary ozonides reveals a close similarity between the gas-phase and the liq uid-phase ozonolysis of alkenes. Copyright (C) 1996 Elsevier Science L td