REDUCTIVE DEHALOGENATION OF ALIPHATIC VIC-DIHALIDES WITH METALLIC SAMARIUM IN A METHANOLIC MEDIUM

Citation
R. Yanada et al., REDUCTIVE DEHALOGENATION OF ALIPHATIC VIC-DIHALIDES WITH METALLIC SAMARIUM IN A METHANOLIC MEDIUM, Tetrahedron letters, 37(52), 1996, pp. 9313-9316
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
52
Year of publication
1996
Pages
9313 - 9316
Database
ISI
SICI code
0040-4039(1996)37:52<9313:RDOAVW>2.0.ZU;2-Y
Abstract
In the title reaction, eight vic-dibromides and three vinylene dibromi des gave the corresponding debromination products (alkenes and alkynes ) at room temperature under neutral condition and an argon atmosphere. 2,3-Dibromosuccinic acid derivatives gave overreduction products or a n unusual coupling dimer. Copyright (C) 1996 Elsevier Science Ltd