DIRECT OBSERVATION OF ORTHOGONAL ORIENTATION OF AN AROMATIC RING ATTACHED TO THE CARBENE CARBON IN FISCHER CARBENE COMPLEXES IN SOLUTION - DIASTEREOTOPICITY OF BENZYL PROTONS AS A STEREOCHEMICAL PROBE

Authors
AMIN SR JAYAPRAKASH KN NANDI M SATHE KM SARKAR A
Citation
Sr. Amin et al., DIRECT OBSERVATION OF ORTHOGONAL ORIENTATION OF AN AROMATIC RING ATTACHED TO THE CARBENE CARBON IN FISCHER CARBENE COMPLEXES IN SOLUTION - DIASTEREOTOPICITY OF BENZYL PROTONS AS A STEREOCHEMICAL PROBE, Organometallics, 15(16), 1996, pp. 3528-3533
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
16
Year of publication
1996
Pages
3528 - 3533
Database
ISI
SICI code
0276-7333(1996)15:16<3528:DOOOOO>2.0.ZU;2-G
Abstract
Diastereotopicity of methylene protons of benzyloxy and benzylamino gr oups in Fischer carbene complexes serves as a stereochemical probe to reveal orthogonal orientation of the aromatic rings attached to the ca rbene carbon with respect to the metal-carbene pi-plane in solution.