POLYMERIZATION OF AN AZASTYRENE DERIVATIVE .1. 1,6-ADDITION POLYMERIZATION OF 2,6-DIISOPROPYL-N-METHYLENEANILINE

Authors
HASHIDZUME A KAJIWARA A HARADA A KAMACHI M
Citation
A. Hashidzume et al., POLYMERIZATION OF AN AZASTYRENE DERIVATIVE .1. 1,6-ADDITION POLYMERIZATION OF 2,6-DIISOPROPYL-N-METHYLENEANILINE, Macromolecular rapid communications, 17(8), 1996, pp. 529-537
Citations number
26
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
17
Issue
8
Year of publication
1996
Pages
529 - 537
Database
ISI
SICI code
1022-1336(1996)17:8<529:POAAD.>2.0.ZU;2-H
Abstract
The polymerizability of an azastyrene derivative, 2,6-diisopropyl-N-me thyleneaniline (DiPMAn), was studied. Although DiPMAn could not be pol ymerized by radical and anionic initiators, it was polymerized with ca tionic initiators, such as trifluoroacetic acid (TFA), TiCl4-TFA, and SnCl4-TFA. The polymer is formed by 1,6-addition with electrophilic su bstitution of an activated monomer in para-position of the aromatic ri ng.