INVESTIGATION OF RADICAL PAIRS PRODUCED UPON PULSE ACTION OF ELASTIC-WAVES ON THE YLCATECHOL-3,6-DI-TERT-BUTYL-O-BENZOQUINONE-SULFUR SYSTEM

Citation
Ai. Aleksandrov et al., INVESTIGATION OF RADICAL PAIRS PRODUCED UPON PULSE ACTION OF ELASTIC-WAVES ON THE YLCATECHOL-3,6-DI-TERT-BUTYL-O-BENZOQUINONE-SULFUR SYSTEM, Russian chemical bulletin, 45(4), 1996, pp. 819-823
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
4
Year of publication
1996
Pages
819 - 823
Database
ISI
SICI code
1066-5285(1996)45:4<819:IORPPU>2.0.ZU;2-Z
Abstract
The pulse action of elastic waves on polycrystalline mixtures of 3,6-d i-tert-butylcatechol and 3,6-di-tert-butyl-o-benzoquinone produces rad ical pairs stable at room temperature, and the addition of polycrystal line sulfur considerably increases their yield. The dependences of for mation and decay rates of paramagnetic centers bn the composition of t he mixture were studied. The threshold character of formation of param agnetic centers at various powers of elastic wave pulse was establishe d.