T. Grunewald et Ca. Helm, COMPUTER-CONTROLLED EXPERIMENTS IN THE SURFACE FORCES APPARATUS WITH A CCD-SPECTROGRAPH, Langmuir, 12(16), 1996, pp. 3885-3890
We present a computer-controlled technique to measure the distance-dep
endent forces in the surface forces apparatus. The power of our setup
is shown by a measurement of the repulsive forces between mica surface
s immersed in a 0.01 M NaCl solution. At close distances we find an os
cillatory force with a periodicity of 0.30 nm, which roughly correspon
ds to the diameter of a water molecule. For the distance determination
we use the standard interferometric technique: the interferometer con
sists of a medium sandwiched between two mica sheets of equal thicknes
s silvered on the backside. The surface separation is measured by comp
aring the resonance wavelength to the one obtained from contacting mic
a sheets. By substitution of the eye by a CCD-camera we improve the re
producibility of the method and we can determine the cavity parameters
quantitatively.