EFFECT OF 3-FORMYLCHROMONES SUBSTITUTED WITH 4-AMINOSALICYLIC ACID AND SOME OTHER ANILINE DERIVATIVES ON PHOTOSYNTHESIS INHIBITION IN SPINACH-CHLOROPLASTS
K. Kralova et al., EFFECT OF 3-FORMYLCHROMONES SUBSTITUTED WITH 4-AMINOSALICYLIC ACID AND SOME OTHER ANILINE DERIVATIVES ON PHOTOSYNTHESIS INHIBITION IN SPINACH-CHLOROPLASTS, Biologia plantarum, 38(3), 1996, pp. 397-404
The inhibitory effect was investigated of 16 different 3-formylchromon
e derivatives, the condensation products of 6-R(1)-3-formylchromone wi
th 4-aminosalicylic acid and of the adducts of 6-R(1)-3-formylchromone
with n-alcohols and aminosalicylic acids or some other derivatives of
aniline, on the photochemical activity of spinach chloroplasts. The i
nhibitory activity of the compounds studied correlated with the lipoph
ilicity of the R(1) and R(2) (alkoxy) substituents. Using fluorescence
study it was found that the site of action of the studied effecters i
s photosystem (PS) 2. By EPR spectroscopy it was confirmed that the st
udied effecters interact with the intermediates Z(+)/Y+ which are situ
ated in D 1 and D 2 proteins on the donor side of PS 2 which is reflec
ted in a partial decrease in the photosynthetic electron flow through
PS 2 to PS 1. It was found that the core of PS 2 is not damaged.