S. Dorfman et D. Fuks, DIFFUSIVITY OF CARBON IN THE COPPER MATRIX - INFLUENCE OF ALLOYING, Composites. Part A, Applied science and manufacturing, 27(9), 1996, pp. 697-701
The heights of diffusion barriers for copper-based composite materials
with carbon whiskers or fibers are calculated. It is shown that the a
lloying of the matrix by an additional element, substituting copper in
an interstitial Cu-C solid solution, changes the value of the barrier
and the migration entropy. This substitutional impurity influences th
e diffusion of the carbon-copper matrix. Zirconium as the best alloyin
g element for preventing the diffusion of carbon in Cu-C alloy is pred
icted.