STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .96. NUCLEOPHILICITY OF THE ISOCYANO CARBON-ATOM IN DIETHYL ISOCYANOMETHYLPHOSPHONATE - FIRST GENERATION OF A PHOSPHORYLATED NITRILE YLIDE AND NEW SYNTHESES OF PYRROLINEPHOSPHONATES AND PYRROLEPHOSPHONATES

Authors
HUANG WS ZHANG YX YUAN CY
Citation
Ws. Huang et al., STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .96. NUCLEOPHILICITY OF THE ISOCYANO CARBON-ATOM IN DIETHYL ISOCYANOMETHYLPHOSPHONATE - FIRST GENERATION OF A PHOSPHORYLATED NITRILE YLIDE AND NEW SYNTHESES OF PYRROLINEPHOSPHONATES AND PYRROLEPHOSPHONATES, Journal of the Chemical Society. Perkin transactions. I, (15), 1996, pp. 1893-1895
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
15
Year of publication
1996
Pages
1893 - 1895
Database
ISI
SICI code
0300-922X(1996):15<1893:SOOC.N>2.0.ZU;2-G
Abstract
Reactions of acyl chlorides with diethyl isocyanomethylphosphonate aff ord alpha-ketoimidoyl chlorides which, when treated with triethylamine , provide a new class of nitrile ylides. These species react in situ w ith alkenes by a 1,3-dipolar cycloaddition mechanism to give phosphory l pyrrolines or pyrroles.