ECE AND DISP PROCESSES AT CHANNEL ELECTRODES - ANALYTICAL THEORY

Authors
LESLIE WM ALDEN JA COMPTON RG SILK T
Citation
Wm. Leslie et al., ECE AND DISP PROCESSES AT CHANNEL ELECTRODES - ANALYTICAL THEORY, Journal of physical chemistry, 100(33), 1996, pp. 14130-14136
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
33
Year of publication
1996
Pages
14130 - 14136
Database
ISI
SICI code
0022-3654(1996)100:33<14130:EADPAC>2.0.ZU;2-9
Abstract
Analytical theory is developed for ECE and DISP1 reactions occurring a t channel electrodes. Simple expressions are presented which allow the ready mechanistic interpretation of experimental data and the deducti on of corresponding rate constants. These are shown to be in excellent agreement with numerical simulations and with experiments conducted o n the reductions of o-bromonitrobenzene in dimethylformamide solution and of p-bromonitrobenzene in acetonitrile in the presence of light of wavelength 325 nm.