THE ROLE OF PHOTOINITIATOR SYSTEMS ON THE EFFECTIVENESS OF PHOTOCURING OF DICYCLOPENTADIENE ACRYLATE (DCPA) HOMOPOLYMER AND ETHYL ACRYLATE (EA) AND DCPA EA COPOLYMERS/

Authors
EISELE G FOUASSIER JP REEB R
Citation
G. Eisele et al., THE ROLE OF PHOTOINITIATOR SYSTEMS ON THE EFFECTIVENESS OF PHOTOCURING OF DICYCLOPENTADIENE ACRYLATE (DCPA) HOMOPOLYMER AND ETHYL ACRYLATE (EA) AND DCPA EA COPOLYMERS/, Die Angewandte makromolekulare Chemie, 239, 1996, pp. 169-190
Citations number
32
Categorie Soggetti
Polymer Sciences
Journal title
Die Angewandte makromolekulare Chemie → ACNP
ISSN journal
00033146
Volume
239
Year of publication
1996
Pages
169 - 190
Database
ISI
SICI code
0003-3146(1996)239:<169:TROPSO>2.0.ZU;2-5
Abstract
The photocrosslinking efficiency of a series of commercial photoinitia tors and multicomponent photosensitive systems on uncrosslinked acryli c matrices has been estimated. Copolymers used for this study are tric yclo[5.2.1.0(2,6)]dec-4-en-8-yl acrylate/ethyl acrylate copolymers of variable composition (100/0, 40/60, 20/80, 0/100) synthesized in solut ion by a free-radical process. The irradiations were carried out at la rge wavelengths (lambda greater than or equal to 310 nm). Systems of b enzophenone/benzoyl peroxide led to really fast crosslinking kinetics for 10 min of irradiation.