Authors
Citation
J. Srinivas et al., CRYSTAL-STRUCTURE OF DIPHENYL)(MORPHOLINO)PHOSPHINIMINOCYCLOTRITHIAZENE, Journal of chemical crystallography, 26(6), 1996, pp. 403-406
Citations number
17
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
ISSN journal
10741542
Volume
26
Issue
6
Year of publication
1996
Pages
403 - 406
Database
ISI
SICI code
1074-1542(1996)26:6<403:COD>2.0.ZU;2-Q
Abstract
The title compound (C6H5)(2)(OC4H8N)P=N-S3N3 crystallizes in the space
group <P(1)over bar> with unit cell parameters a = 9.3900(2), b = 9.4
747(1), c = 11.3850(3) Angstrom, alpha = 95.73(4), beta = 96.85(6), ga
mma = 104.26(2)degrees, and Z = 2. The tricoordinated sulfur of the cy
clotrithiazene ring deviates from the mean plane of other skeletal ato
ms by 0.683(4) Angstrom. The angle at this atom is the smallest in the
ring and is enclosed by the longest S-N bonds observed in the ring.