ACIDITY OF DIBASIC CARBON ACIDS .4. STRUCTURE AND ION SOLVATION STATEOF DIMETALLIC SALTS OF 9,10-DIHYDROANTHRACENE AND ITS DERIVATIVES IN TETRAHYDROFURAN

Authors
NIR M SHAPIRO IO HOFFMAN RE RABINOVITZ M
Citation
M. Nir et al., ACIDITY OF DIBASIC CARBON ACIDS .4. STRUCTURE AND ION SOLVATION STATEOF DIMETALLIC SALTS OF 9,10-DIHYDROANTHRACENE AND ITS DERIVATIVES IN TETRAHYDROFURAN, Perkin transactions. 2, (8), 1996, pp. 1607-1615
Citations number
33
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
8
Year of publication
1996
Pages
1607 - 1615
Database
ISI
SICI code
0300-9580(1996):8<1607:AODCA.>2.0.ZU;2-R
Abstract
The ion solvation state of dimetallic salts (M = Li-Cs) of 9, 10-dihyd roanthracene (DHA) and its derivatives in THF was studied by UV-VIS an d NMR spectroscopies. The cations are situated on the opposite sides o f the dianion plane in the dimetallic salts. Cation-dianion interactio n stabilized the negative charge of the carbanion. The mechanism of di anion charge stabilization is affected by a phenyl substituent.