ABSOLUTE RATE CONSTANTS FOR ABSTRACTION OF CHLORINE FROM 3 CHLORINATING AGENTS BY ALKYL RADICALS

Authors
TANKO JM BLACKERT JF
Citation
Jm. Tanko et Jf. Blackert, ABSOLUTE RATE CONSTANTS FOR ABSTRACTION OF CHLORINE FROM 3 CHLORINATING AGENTS BY ALKYL RADICALS, Perkin transactions. 2, (8), 1996, pp. 1775-1779
Citations number
40
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
8
Year of publication
1996
Pages
1775 - 1779
Database
ISI
SICI code
0300-9580(1996):8<1775:ARCFAO>2.0.ZU;2-Q
Abstract
Using the cyclopropylcarbinyl --> homoallyl free radical clock, absolu te rate constants for the abstraction of chlorine from molecular chlor ine (Cl-2), tert-butyl hypochlorite (Bu(t)OCl) and N-chloro-3,3-dimeth ylglutarimide (NCG) have been determined (kCl(2)) = 3.0 x 10(10), k(Bu tOCl) = 2.6 x 10(9) and k(NCG) = 3.6 x 10(7), all in l mol(-1) s(-1)).