M. Stojanovic et al., FREQUENCY NOISE-LEVEL OF AS ION-IMPLANTED TIN-TI-SI STRUCTURES, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 115(1-4), 1996, pp. 554-556
This paper presents a possibility of using frequency noise level measu
rements to study the properties of Ti silicides. We have sputter depos
ited sequentially a 100 nm thick titanium layer and a 50 nm TiN layer
on p-type Si (111) wafers. The TiN/Ti/Si structures were implanted wit
h As+ at 350 keV, to doses from 1 X 10(15) to 1 X 10(16) ions/cm(2). T
he projected range of arsenic ions is near Si-Ti interface. The sample
s were annealed in vacuum at temperatures up to 800 degrees C. Methods
of characterization of samples include frequency noise level measurem
ents, Rutherford backscattering, and electrical measurements. Annealin
g induce the Ti-Si reaction, the top TiN layer remaining stable throug
hout the processing. Silicidation depends on the annealing time and te
mperature, and on the implanted dose. In samples implanted up to 5 X 1
0(15) ions/cm(2) the low resistivity TiSi phase is formed at 750 degre
es C. For higher implanted doses silicidation is retarded. In this cas
e TiSi is formed initially, transforming to the TiSi phase for longer
annealing times. Noise spectra show that the noise level depend on the
implanted As dose, and that for some frequencies, the implanted sampl
es have higher noise level compared to the unimplanted samples.