COORDINATION CHEMISTRY OF 8-MEMBERED POLYPHOSPHORUS HETEROCYCLES

Authors
Citation
Eh. Wong, COORDINATION CHEMISTRY OF 8-MEMBERED POLYPHOSPHORUS HETEROCYCLES, Comments on modern chemistry. Part A, Comments on inorganic chemistry, 18(5-6), 1996, pp. 283-304
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
02603594
Volume
18
Issue
5-6
Year of publication
1996
Pages
283 - 304
Database
ISI
SICI code
0260-3594(1996)18:5-6<283:CCO8PH>2.0.ZU;2-T
Abstract
The coordination and reaction chemistry of eight-membered polyphosphor us heterocycles is outlined with particular focus on a versatile tetra phosphoxane P4O4 ring system. This ligand's coordination modes include s an exo-ditopic form which has been used to prepare a mixed-valent fa mily of heterobimetallic complexes with conserved cage structures suit able for the study of metal-metal interactions.