SELECTIVE DEALKYLATION OF ALKYLPHENOLS ON METAL SULFATES AND HYDROSULFATES

Citation
Yt. Gorodetskii et Pn. Galich, SELECTIVE DEALKYLATION OF ALKYLPHENOLS ON METAL SULFATES AND HYDROSULFATES, Petroleum chemistry, 36(2), 1996, pp. 144-154
Citations number
18
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
ISSN journal
09655441
Volume
36
Issue
2
Year of publication
1996
Pages
144 - 154
Database
ISI
SICI code
0965-5441(1996)36:2<144:SDOAOM>2.0.ZU;2-I
Abstract
An investigation has been made of the physicochemical and catalytic pr operties of metal sulphates and hydrosulphates and of supported metal sulphates and hydrosulphates in the selective monodealkylation of phen ols. It was established that water molecules and the nature of the met al cation in the sulphates determine their catalytic properties. The m echanism of the reaction was found. (C) 1996 Elsevier Science Ltd.