In recent years the interest of this investigator has been attracted t
o a series of new compounds in which a cyclopentanoperhydrophenanthren
e system is condensed with various heterocyclic rings. As was to be ex
pected, the addition of heterocycles to steroids often leads to a chan
ge of their physiological activity and the appearance of new interesti
ng biological properties. Since the numerous data on the synthesis and
properties of the steroidal oxazoles, oxazolines, and oxazolidines ar
e scattered, this stimulated us to write the present review, in which
the literature published up to the end of 1994 is systematized.