STERIC AND ELECTRONIC EFFECTS ON THE PARTITIONING OF A PERSULFINYL INTERMEDIATE ALONG THE PHYSICAL QUENCHING AND CHEMICAL-REACTION CHANNELS

Authors
CLENNAN EL GREER A
Citation
El. Clennan et A. Greer, STERIC AND ELECTRONIC EFFECTS ON THE PARTITIONING OF A PERSULFINYL INTERMEDIATE ALONG THE PHYSICAL QUENCHING AND CHEMICAL-REACTION CHANNELS, Tetrahedron letters, 37(34), 1996, pp. 6093-6096
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
34
Year of publication
1996
Pages
6093 - 6096
Database
ISI
SICI code
0040-4039(1996)37:34<6093:SAEEOT>2.0.ZU;2-3
Abstract
The rate constants, k(T), k(r), and k(Q), corresponding to the substra te induced total removal, chemical removal, and physical removal of si nglet oxygen, respectively, have been measured for a series of sulfena mides. The structural effects on the partitioning of the persulfinamid e intermediate along the chemical and physical deactivation pathways i s discussed. Copyright (C) 1996 Elsevier Science Ltd