EFFICIENT METHOD FOR INVERSION OF SECONDARY ALCOHOLS BY REACTION OF CHLOROMETHANESULFONATES WITH CESIUM ACETATE

Authors
SHIMIZU T HIRANUMA S NAKATA T
Citation
T. Shimizu et al., EFFICIENT METHOD FOR INVERSION OF SECONDARY ALCOHOLS BY REACTION OF CHLOROMETHANESULFONATES WITH CESIUM ACETATE, Tetrahedron letters, 37(34), 1996, pp. 6145-6148
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
34
Year of publication
1996
Pages
6145 - 6148
Database
ISI
SICI code
0040-4039(1996)37:34<6145:EMFIOS>2.0.ZU;2-K
Abstract
Inversion of a variety of secondary alcohols using the (chloromethylsu lfonyl)oxy group as a favorable leaving group with cesium acetate in t he presence of 18-crown-6 has been performed to give the inverted acet ates in high yields. Copyright (C) 1996 Elsevier Science Ltd