We present results of an experimental and theoretical investigation of
H- formation in collisions of 1-4 keV positive and negative hydrogen
ions with clean Al surfaces. The scattered ion fractions were investig
ated in a large angular range extending from 2 to 40 degrees with resp
ect to the surface plane. This allowed us to investigate the character
istics of the resonant charge transfer process in a wide range of coll
ision velocities normal to the surface, allowing us in particular to r
each the domain where small atom-surface distances play an important r
ole. Results of theoretical calculations could thus be tested in a mor
e stringent manner than in previous high grazing-incidence experiments
of Wyputta et al.