V. Drouot et al., EVALUATION OF H-PLASMA AND THERMAL OXIDE DESORPTION PROCEDURES FOR MBE REGROWTH OF AN INP INGAAS/INP QUANTUM-WELL/, Semiconductor science and technology, 11(8), 1996, pp. 1178-1184
An InGaAs single quantum well structure has been used to investigate t
he effect of H-plasma exposure for oxide removal and subsequent regrow
th on InP surfaces. In addition, the H-plasma desorption is compared w
ith the usual technique of thermal desorption of the oxide. Assessment
of the optical quality of the regrowth interface has been achieved,by
photoluminescence (PL), photoluminescence excitation (PLE) and photor
eflectance (PR) spectroscopy studies of the quantum well grown directl
y on the regrowth interface. It is shown that the effect of the H-plas
ma itself on the InP surface can be minimized by applying a positive b
ias of +30 V to the substrate or by annealing the substrate, For both
the H-plasma and the thermal surface cleaning treatments, the regrowth
procedure on air/UV-ozone exposed samples introduces non-radiative de
fects which Strongly degrade the room-temperature PC efficiency. The r
egrowth procedure also induces a defect-related peak in the low-temper
ature PL spectra, 15 meV below the quantum well intrinsic PL line. The
defect concentration is higher in the case of the H-plasma desorption
than in thermal desorption, as deduced from PL measurements. The PLE
and PR measurements confirm that the interface disorder is also higher
in the H-plasma cleaned sample.