CRYSTAL-STRUCTURE AND SPECTRA OF COMPLEX [EU(O-ABA)(3)BIPY]BIPY

Authors
Citation
Lp. Jin et al., CRYSTAL-STRUCTURE AND SPECTRA OF COMPLEX [EU(O-ABA)(3)BIPY]BIPY, Polyhedron, 15(22), 1996, pp. 4069-4077
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
15
Issue
22
Year of publication
1996
Pages
4069 - 4077
Database
ISI
SICI code
0277-5387(1996)15:22<4069:CASOC[>2.0.ZU;2-C
Abstract
[Eu(o-ABA)(3)bipyl]bipy (where o-ABA = o-aminobenzoate and bipy = 2,2' -bipyridine) was synthesized and characterized by X-ray diffraction, I R and Raman spectra. In the crystal the compound exists as a dimer, ea ch europium atom is eight-coordinated and has one bipyridine molecule, one bidentate carboxylate group and four oxygen atoms from bridging c aboxylates. Luminescence data show that the complex contains one Eu-II I ion in a site with low symmetry. Copyright (C) 1996 Elsevier Science Ltd