PREPARATION OF ENVIRONMENTALLY FRIENDLY ALKYLGLUCOSIDE SURFACTANTS USING ZEOLITES AS CATALYSTS

Citation
A. Corma et al., PREPARATION OF ENVIRONMENTALLY FRIENDLY ALKYLGLUCOSIDE SURFACTANTS USING ZEOLITES AS CATALYSTS, Journal of catalysis, 161(2), 1996, pp. 713-719
Citations number
24
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00219517
Volume
161
Issue
2
Year of publication
1996
Pages
713 - 719
Database
ISI
SICI code
0021-9517(1996)161:2<713:POEFAS>2.0.ZU;2-H
Abstract
Fischer glycosidation of D-glucose and n-butanol has been carried out successfully using different acid zeolites as catalysts. Both butylglu cofuranoside and pyranoside are obtained during reaction. It has been found that large pore tridirectional zeolites with high Si/Al ratios s uch as faujasite and beta are the most suitable catalysts. The influen ce of the molar ratio alcohoyl/D-glucose on the selectivity to alkylmo nosaccharide has been also studied. (C) 1996 Academic Press, Inc.