The supernova remnant 3C 391 (G31.9 + 0.0) was observed using the ROSA
T Position Sensitive Proportional Counter (PSPC). The PSPC image revea
ls centrally concentrated X-ray emission inside the radio shell, antic
orrelated with the radio image. The northwestern half of the remnant h
as a strong radio shell and weak, centrally concentrated X-ray emissio
n. In contrast, the southeastern half has strong central X-ray emissio
n and weak radio emission. A spectral analysis combining PSPC and Eins
tein IPC data indicates that the X-ray emission arises from a thermal
plasma that has not attained ionization equilibrium, though a nontherm
al model can be rejected only with 90% confidence. There is evidence,
al the 90% confidence level, of slightly enhanced abundances of the in
termediate alpha-burning elements, Mg, Si, and S. The best-fit N-H is
2.4 x 10(22) cm(-2) and kT is 0.5 keV (T = 5.9 x 10(6) K). The central
ly concenc trated morphology and the probable thermal origin of the X-
ray emission along with the radio shell suggest that 3C 391 is similar
to W44 and W28. There are spectral variations between the northwester
n and southeastern parts of the remnant: either the northwest has high
er N-H or the southeastern part has lower temperature, the former bein
g more consistent with the X-ray morphology. The difference in N-H is
large enough to account far the reduced X-ray surface brightness in th
e northwest, and the density in the northwest is higher than that in t
he southeastern shell. The X-ray data are consistent with the idea tha
t the progenitor supernova has exploded just inside a molecular cloud,
but close to the edge. The northwestern structure is created by the p
ropagation of the supernova shock into the cloud while the enhanced ce
ntral X-ray emission arises from evaporation of clumps from the edge o
f the cloud trapped within the remnant. The southeastern radio and X-r
ay emission represent a ''breakout'' of the shock into low-density, in
tercloud material.