EFFECT OF A PROXIMAL SUBSTITUENT ON THE TRIRUTHENIUM DODECACARBONYL-CATALYZED REDUCTIVE CARBONYLATION OF NITROARENES

Authors
BOLZACCHINI E LUCINI R MEINARDI S ORLANDI M RINDONE B
Citation
E. Bolzacchini et al., EFFECT OF A PROXIMAL SUBSTITUENT ON THE TRIRUTHENIUM DODECACARBONYL-CATALYZED REDUCTIVE CARBONYLATION OF NITROARENES, Journal of molecular catalysis. A, Chemical, 110(3), 1996, pp. 227-233
Citations number
32
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
110
Issue
3
Year of publication
1996
Pages
227 - 233
Database
ISI
SICI code
1381-1169(1996)110:3<227:EOAPSO>2.0.ZU;2-V
Abstract
Three nitroarenes were submitted to Ru-3(CO)(12)-catalyzed reductive c arbonylation in acetonitrile and in cis-cyclooctene. The main reaction products were the corresponding amines, ureas and six- or five-member ed cyclization products. Optimization of the reaction varying the temp erature, the CO pressure, the catalyst/substrate ratio and the reactio n time and a statistical analysis of conversion and selectivity data a llow to suggest a reaction mechanism in some reaction conditions.