Ls. Johansson et al., THE INFLUENCE OF METAL-CONTAINING COMPOUNDS ON ENHANCEMENT AND INHIBITION OF ASPHALT OXIDATION, Fuel science & technology international, 14(8), 1996, pp. 1143-1159
Addition of lime to paving asphalts is known to inhibit oxidative agin
g of pavements. The mechanism of the action of lime in retarding oxida
tion is not known. In this work, an asphalt was mixed with a vanadium
chelate that is known to strongly promote oxidation in asphalts. This
enhancement of oxidation was largely neutralized when the mixtures wer
e combined with hydrated lime. It is possible that lime acts by suppre
ssing the catalytic activity of naturally occurring vanadium compounds
that occur in almost all asphalts, although other mechanisms for the
action of lime are also possible. The use of vanadium compounds in asp
halt aging tests also is discussed.