SYNERGISTIC EXTRACTION OF NI(II) BY MIXTURES OF LIX-63 AND BIS-(2-ETHYLHEXYL)PHOSPHORIC OR DI-N-OCTYLPHOSPHINIC ACIDS IN TOLUENE

Authors
ELIZALDE MP COX M AGUILAR M
Citation
Mp. Elizalde et al., SYNERGISTIC EXTRACTION OF NI(II) BY MIXTURES OF LIX-63 AND BIS-(2-ETHYLHEXYL)PHOSPHORIC OR DI-N-OCTYLPHOSPHINIC ACIDS IN TOLUENE, Solvent extraction and ion exchange, 14(5), 1996, pp. 833-848
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Solvent extraction and ion exchange → ACNP
ISSN journal
07366299
Volume
14
Issue
5
Year of publication
1996
Pages
833 - 848
Database
ISI
SICI code
0736-6299(1996)14:5<833:SEONBM>2.0.ZU;2-A
Abstract
The extraction equilibria of Ni(II) from nitrate medium by mixtures of the active component in the commercial LIX 63, 5,8-diethyl-7-hydroxyd odecan-6-oxime (HDEHO), and bis(2-ethylhexyl)phosphoric (HDEHP) or di- n-octylphosphinic (H[DOP]) acids dissolved in toluene have been studie d. Large synergistic effects have been obtained in both cases and mixe d metallic species have been proposed to explain the experimental extr action of Ni(II) by these mixtures. Equilibrium constant values of the extracted species are also given.