The prepyrolysis of delignified wheat straw is studied. Aqueous alkali
ne (NaOH-Na2CO3, NaOH-NaHCO3) as well as organosolv alkaline (NaOH-eth
anol, NaOH-isopropanol) delignification methods were used. Pretreated
straw was thermochemically converted to a solid bio-fuel at 270 degree
s for 30 min. Prepyrolysis dry yield and gross caloric value of the ma
terial produced were determined to characterize the behaviour of pretr
eated material during heating and the effects of delignification. The
prepyrolytic behaviour of the pretreated material can be described by
simple mathematical formulae. In particular, prepyrolysis dry yield is
generally a linear function of lignin content, i.e. degree of deligni
fication; moreover, the caloric value of the solid fuel produced after
prepyrolysis can also be linearly expressed with lignin content or de
lignification.