SYNTHESIS AND STRUCTURE OF THE ADDUCT CL3ASO-CENTER-DOT-ASF5

Authors
PETERSEN J LORK E MEWS R
Citation
J. Petersen et al., SYNTHESIS AND STRUCTURE OF THE ADDUCT CL3ASO-CENTER-DOT-ASF5, Chemical communications, (16), 1996, pp. 1897-1898
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1996
Pages
1897 - 1898
Database
ISI
SICI code
1359-7345(1996):16<1897:SASOTA>2.0.ZU;2-E
Abstract
The relatively thermally stable adduct Cl3AsO . AsF5 1 is prepared in high yield from AsCl4+AsF6- and Me(3)SiOSiMe(3) in liquid SO2 at -40 d egrees C, and originally surprisingly isolated from the reaction of Pr Cl3 and AgAsF6 in liquid SO2; the X-ray crystal structure of 1 is comp ared with that of Cl3PO . AsF5.