THE REACTION OF ELECTROPHILIC TERMINAL PHOSPHINIDENE COMPLEXES WITH ENOLIZABLE KETONES - C-H VS O-H VS C-C INSERTION OF PHOSPHORUS

Authors
INUBUSHI Y HUY NHT MATHEY F
Citation
Y. Inubushi et al., THE REACTION OF ELECTROPHILIC TERMINAL PHOSPHINIDENE COMPLEXES WITH ENOLIZABLE KETONES - C-H VS O-H VS C-C INSERTION OF PHOSPHORUS, Chemical communications, (16), 1996, pp. 1903-1904
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1996
Pages
1903 - 1904
Database
ISI
SICI code
1359-7345(1996):16<1903:TROETP>2.0.ZU;2-I
Abstract
Transient [PhP-->W(CO)(5)], as generated from the appropriate 7-phosph anorbornadiene precursor, reacts at 120 degrees C with various enoliza ble ketones or beta-diketones to give the products resulting from the insertion of phosphorus into either the alpha-CH, the enol OH, or the acyl-CH2 bonds.