PROPYLENE CARBONATE STABILIZED NANOSTRUCTURED PALLADIUM CLUSTERS AS CATALYSTS IN HECK REACTIONS

Authors
REETZ MT LOHMER G
Citation
Mt. Reetz et G. Lohmer, PROPYLENE CARBONATE STABILIZED NANOSTRUCTURED PALLADIUM CLUSTERS AS CATALYSTS IN HECK REACTIONS, Chemical communications, (16), 1996, pp. 1921-1922
Citations number
33
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1996
Pages
1921 - 1922
Database
ISI
SICI code
1359-7345(1996):16<1921:PCSNPC>2.0.ZU;2-1
Abstract
Nanostructured Pd clusters, prepared either electrochemically using a sacrificial Pd anode or by thermolysis of Pd(O(2)CMe)(2), are stable i n propylene carbonate even at 140-155 degrees C; such colloidal soluti ons catalyse Heck reactions in the absence of phosphine ligands.